Department of Bioproducts and Biosystems

Biorefineries

Biorefineries research group is led by Prof. Herbert Sixta. The group's research covers the entire value chain from the fractionation of the lignocellulosic biomass to valorization of the isolated biopolymers, with the aim of sustainably producing commodities analogous to fossil-based products.
CHEM_Bio_Marianna_Granatier_From wood to fiber
Marianna Granatier, From wood to fiber

Research themes:

1. Biomass fractionation - chemical pulping refineries and novel fractionation processes:

We investigate radically new energy and resource efficient production technologiesfor chemical pulping, e.g. Kraft-Oxygen Delignification (KrOxy) process and new dissolving pulp technologies. In addition, our research group develops novel biomass fractionation processes based on the utilization of Biomass valorisationsupercritical water and green solvents, e.g. gamma-valerolactone (GVL).

 

2. Biomass valorisation:

Cellulose: We study conversion of cellulose e.g. into man-made cellulose fibers and all-cellulose composites.

Hemicelluloses: Our research topics include the valorisation of xylan from alkaline extractions, production of xylo-oligosaccharides and catalytic conversion of biomass-derived sugars into furans.

Lignin: Lignin is an interesting biomass component which can be converted into valuable products such as bio-oil. Lignin-cellulose blends can be used e.g. as precursor fibers for carbon fibers, or as natural dye in textiles.

Our versatile reactor portfolio enables flexible pulping experiments from small lab-scale (30 mL) to pilot scale (10 L), including both traditional (prehydrolysis) kraft and novel Organosolv processes. Elemental-Chlorine-Free (ECF) and Total-Chlorine-Free (TCF) bleaching techniques are readily available.

Our flagship research in biomass valorization is the production of novel man-made cellulose fibers for the circular economy by the dry-jet-wet spinning Ioncell® process, which convert cellulose from virgin wood pulp or cellulosic textile waste into high-quality, high-strength textile fibers. In addition, our research group is equipped with fiber characterization equipment and yarn spinning machinery. We also investigate in the conversion of extracted hemicelluloses and lignin to high value products such as furanic platform chemicals, monoaromatic compounds and bio-oil. Our lab developed advanced chromatography methods (HPLC, CE, IC, GPC) for comprehensive analysis of complex product mixtures.

 

Examples of ongoing research projects:

  • Trash-2-Cash (EU Horizon 2020)
  • SolvRec (Business Finland)
  • iCom (Business Finland)
  • ALL-CELL (FiDiPro, Prof. Tatiana Budtova)
  • WoCaFi (ERC starting grant, Dr. Michael Hummel)
  • Tekide (ERDF)

ALL-CELL: From ultra-light to ultra-strong all-cellulose composites via green processing

Finland Distinguished Professor grant awarded to Prof. Tatiana Budtova (Center for Materials Forming of MINES ParisTech, France). The goal of the 4-year project (started 2016) is to imagine, prepare and characterize new fully bio-based materials, all-cellulose composites.

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Feng Chen, Tatiana Budtova and Oona Korhonen - ALL-CELL team. Photo by Eveliina Jutila
Aalto University / Ioncell logo

Ioncell

Ioncell-F is a technology that turns used textiles, pulp or even old newspapers into new textile fibers sustainably and without harmful chemicals. The process converts cellulose into fibers which in turn can be made into long-lasting fabrics.

Read more about the Ioncell process and our projects at ioncell.fi!

Twitter: @IoncellFibers

ioncell.fi

Awards:

The Ioncell-F process was granted the Global Change Award 2016 by the H&M Conscious Foundation, the Paper Recycling Award 2015 of the European Recovered Paper Council (ERPC), and the DIA Innovation Award 2018.

Ioncell fibers:

President Sauli Niinistö and Jenni Haukio at 2018 Finnish Independence Day reception. Photo: Vesa Moilanen/Lehtikuva

Mrs. Jenni Haukio’s gala dress in the Independence Day Reception 6.12.2018; photo: Vesa Moilanen, Lehtikuva. Textile design: Helmi Liikanen (ARTS), dress design: Emma Saarnio (ARTS)

CHEM_Bio_Ioncell_from jeans to scarf

A scarf made of Ioncell® fibers from recycled waste cotton and given to president Macron

CHEM_Bio_IOncell Marimekko dress

Marimekko’s Unikko dress. It was produced form Ioncell®/Tencel™ blend woven fabric. Photo: Sebastian Johansson, dress design: Riikka Buri, Marimekko

CHEM_Bio_Ioncell dress group

The Ioncell dress group

γ-valerolactone biorefinery

γ-valerolactone pulping is a novel organic solvent fractionation process developed by Professor Herbert Sixta’s Biorefineries research group.

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GVL biorefinery Photo: Aalto University / Anni Hanén
CHEM_Bio_Herbert Sixta

We urge not only for investment in pulping research, but also for the commitment of young researchers.Together we make pulping great again!

Herbert Sixta, head of the research group
Ioncell thread on four different colors

The textile industry needs sustainable fibers produced from renewable or recycled sources, which can be recycled at the end of their life and which do not produce micro-plastics.  The demand for textile fibers is growing due to population growth and living standards. Currently, most textile fibers are synthetic, e.g. polyester, and are made from non-renewable sources. Cotton cultivation causes environmental problems due to the high consumption of irrigation water, pesticides and fertilizers. When textiles made of synthetic fibres are washed and worn, small fragments are released, causing microplastic contamination.

Aalto University offers the opportunity to study the raw material chemistry and process engineering necessary for the development of a sustainable textile industry, thereby combining materials research with textile and fashion design.

Production of commodities from biomass is the most viable option in the foreseeable future to mitigate the climate changes.

The raw materials of novel man-made cellulose fibers that we are developing in our research group are virgin pulp and recycled cotton waste. Cellulose pulp is made from smaller trees, and thinning stimulates the growth of remaining trees, thereby increasing carbons storage. When pulp is used for long-lasting products like textiles, the carbon is stored in the product. The recycling of cellulosic textiles even prolongs the carbon sink

CHEM_Bio_Biorefineries group

Latest publications:

Vapor-Liquid Equilibrium of Ionic Liquid 7-Methyl-1,5,7-triazabicyclo[4.4.0]dec-5-enium Acetate and Its Mixtures with Water

Zachariah Steven Baird, Petri Uusi-Kyyny, Joanna Witos, Antti H. Rantamäki, Herbert Sixta, Susanne K. Wiedmer, Ville Alopaeus 2020 Journal of Chemical and Engineering Data

Unidirectional All-Cellulose Composites from Flax via Controlled Impregnation with Ionic Liquid

Feng Chen, Daisuke Sawada, Michael Hummel, Herbert Sixta, Tatiana Budtova 2020 Polymers

Solubility study of lignin in industrial organic solvents and investigation of electrochemical properties of spray-coated solutions

Arman Dastpak, Tainise Vergara Lourencon, Mikhail Balakshin, Farhan Hashmi, Mari Lundström, Benjamin P. Wilson 2020 Industrial Crops and Products

Immobilization of natural lipid biomembranes and their interactions with choline carboxylates. A nanoplasmonic sensing study

Filip Duša, Wen Chen, Joanna Witos, Antti H. Rantamäki, Alistair W.T. King, Evangelos Sklavounos, Michal Roth, Susanne K. Wiedmer 2020 Biochimica et Biophysica Acta - Biomembranes

Furfural production from xylose and birch hydrolysate liquor in a biphasic system and techno-economic analysis

Gerardo Gómez Millán, Rahul Prasad Bangalore Ashok, Pekka Oinas, Jordi Llorca, Herbert Sixta 2020 Biomass Conversion and Biorefinery

New insights into the air gap conditioning effects during the dry-jet wet spinning of an ionic liquid-cellulose solution

Chamseddine Guizani, Kaarlo Nieminen, Marja Rissanen, Sauli Larkiala, Michael Hummel, Herbert Sixta 2020 Cellulose

Effect of metal formates on hydrothermolysis of organosolv lignin for the production of bio-oil

Syed Farhan Hashmi, Leena Pitkänen, Anne Usvalampi, Heidi Meriö-Talvio, Kyösti Ruuttunen, Herbert Sixta 2020 Fuel

Influence of reaction conditions on solvolysis of organosolv lignin using water and green organic co-solvents as reaction medium

Farhan Hashmi, Heidi Meriö-Talvio, Kyösti Ruuttunen, Herbert Sixta 2020 Fuel Processing Technology

Cellulose Fibers for High-Performance Textiles Functionalized with Incorporated Gold and Silver Nanoparticles

Simone Haslinger, Yuhang Ye, Marja Rissanen, Michael Hummel, Herbert Sixta 2020 ACS Sustainable Chemistry and Engineering
More information on our research in the Research database.
Research database
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