News

Single-atom dopants in metallic nanoparticles can offer high tunability for plasmonic-catalytic applications

CEST researchers use TDDFT-based calculations to study the tunability of the plasmonic-catalytic properties of nanoparticles
graphic illustratinig metal atoms
Graphic by Dr. Tuomas Rossi

In plasmonic-catalytic nanoparticles a plasmonic metal acts antenna for light absorption, whereas the catalytic metal component facilitates the reaction. Plasmonic nanoparticles can absorb light at certain resonant wavelengths very efficiently. As the light-induced plasmonic excitation in the nanoparticle decays, non-thermal high-energy electrons and holes, so called “hot carriers”, are formed. Hot carriers can interact with nearby molecules and enhance chemical reactions. Typically, the reactions are catalyzed by carriers of certain energies, which is why the ability to control the energies of the hot carriers is important. Experimental investigations of the plasmonic-catalytic properties are challenging and time consuming, but computational tools can reveal quantum mechanical insight and trends.

photo of CEST researcher D. Sorvisto
CEST researcher D. Sorvisto

The CEST group members Daniel Sorvisto, Tuomas Rossi, and Patrick Rinke recently published their computational exploration of single-atom dopant effects in plasmonic nanoparticles. The goal of the study was to analyze the effects of doping on the hot-carrier generation in the nanoparticle and the extent to which hot carriers can be tuned. Computations are based on Kohn-Sham DFT and TDDFT. Two different nanoparticle structures of a few hundred atoms, three different plasmonic metals, and five different catalytic metals are included in the study. Results show that the local hot-carrier generation can be tuned by choosing the right dopant element while the plasmonic response of the nanoparticle as a whole is not significantly affected by the dopant. As the resonant wavelengths of nanoparticles can also be tuned by the overall shape, size, and composition of the nanoparticle, the findings of the study indicate that plasmonic nanoparticles could be simultaneously tailored to absorb light efficiently and generate hot carriers tuned to a specific purpose. An interesting next step would be to study the catalytic performance and include the interactions between the nanoparticles and reactant molecules in the modeling.

The paper is published in The Journal of Physical Chemistry C (doi.org/10.1021/acs.jpcc.3c01998).

  • Published:
  • Updated:

Read more news

Textile Chemistry research group
Research & Art Published:

Making textiles greener, safer, and cooler

Professor Ali Tehrani and his research group focus on something very familiar to us all – textiles.
XX
Campus Published:

PechaKucha event tested the presentation skills of doctoral students at the School of Electrical Engineering

The first PechaKucha at the School of Electrical Engineering challenged the school's doctoral students to present the topics of their dissertation in six minutes. The event was held on Wednesday 22 May at Otaniemi A Grid.
Näytös image. Two sets of legs and shoes in a sepia coloured image.
Research & Art Published:

Aalto University's fashion event Näytös expands into an exhibition

Aalto University's annual fashion event is expanding this year into a two-part show. The traditional runway event Näytös will be joined by a new event, an exhibition called Näyttely.
Nesteen polttoainejalostamon tankit Porvoossa
Cooperation, Research & Art Published:

Collaboration with Aalto brings significant financial benefits to Neste

As a result of the collaboration, Neste is now using digital tools in its fuel research alongside traditional testing.